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112 The EPR signals from intracellular Mn 2+ complexes reveal that, on average, the 6 to 7 coordination sites are occupied by ∼3 to 4.5 water molecules and ∼0.5 to 1.5 N atoms, with most of the remaining ligands from phosphates (inorganic phosphate, phosphorylated metabolites, and nucleic acids), with a negligible contribution from carboxylates