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specific bands were found in both non-inoculated MRS and Gt28L, but the bands at 1,493 cm –1 and 1,516 cm –1 are specific to the extracellular metabolites of LAB and are attributed to C = C (aromatic) vibrations and NH (amide II) deformations, associated with phenolic compounds and microbial peptides ( –1 is specific to Amide I, the typical band for C = O stretching (amide I), highlighting protein content (possible extracellular peptides) and is found in both spectra (Ji et al., 2020)