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Consequently, ncAAs with metal-binding/coordinating capabilities or even act as a catalyst exerting a synergistic catalytic catalysis with metal ions offer a compelling means to bind and influence the characteristics of catalytic metal ions, leading to the creation of artifical metalloenzymes

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Except for the pineal gland, other structures contribute little to circulating concentrations in mammals, since after pinealectomy, melatonin levels are mostly undetectable (12)