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142 Acrolein 365 and crotonaldehyde 366 both form bis-adducts with cysteine through a 1,4-addition to give intermediates 369 or 370 with rates of 220 and 8.9 M −1 s −1 respectively, followed by rapid condensation with a second cysteine to form a thiazolidines 371 and 372 (Scheme 25)